Cellulose Membranes in the Treatment of Spent Deep Eutectic Solvent Used in the Recovery of Lignin from Lignocellulosic Biomass
Ippolitov, Vadim; Anugwom, Ikenna; van Deun, Robin; Mänttäri, Mika; Kallioinen-Mänttäri, Mari (2022-01-13)
Publishers version
Ippolitov, Vadim
Anugwom, Ikenna
van Deun, Robin
Mänttäri, Mika
Kallioinen-Mänttäri, Mari
13.01.2022
Membranes
12
1
MDPI
School of Engineering Science
Julkaisun pysyvä osoite on
https://urn.fi/URN:NBN:fi-fe202201178889
https://urn.fi/URN:NBN:fi-fe202201178889
Tiivistelmä
Ultrafiltration was employed in the purification of spent Deep Eutectic Solvent (DES, a mixture of choline chloride and lactic acid, 1:10, respectively) used in the extraction of lignin from lignocellulosic biomass. The aim of this was to recover different lignin fractions and to purify spent solvent. The results revealed that the commercial regenerated cellulose membranes—RC70PP and Ultracel 5 kDa UF membranes—could be used in the treatment of the spent DES. The addition of cosolvent (ethanol) to the spent DES decreased solvent’s viscosity, which enabled filtration. With two-pass ultrafiltration process with 10 kDa and 5 kDa membranes about 95% of the dissolved polymeric compounds (lignin and hemicelluloses) were removed from the spent DES. The utilized membranes also showed the capability to fractionate polymeric compounds into two fractions—above and under 10,000 Da. Moreover, the 10 kDa cellulose-based membrane showed good stability during a continuous period of three weeks exposure to the solution of DES and ethanol. Its pure water permeability decreased only by 3%. The results presented here demonstrate the possibility to utilize cellulose membranes in the treatment of spent DES to purify the solvent and recover the interesting compounds.
Lähdeviite
Ippolitov, V.; Anugwom, I.; van Deun, R.; Mänttäri, M.; Kallioinen-Mänttäri, M. Cellulose Membranes in the Treatment of Spent Deep Eutectic Solvent Used in the Recovery of Lignin from Lignocellulosic Biomass. Membranes 2022, 12, 86. https://doi.org/10.3390/membranes12010086
Alkuperäinen verkko-osoite
https://www.mdpi.com/2077-0375/12/1/86Kokoelmat
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